With increasing energy demand and advancing carbon neutrality goals, arid regions-key areas for centralized photovoltaic (PV) station development in China-urgently require efficient and accurate remote sensing techniques to support spatial distribution monitoring and ecological impact assessment. Although numerous studies have focused on PV station extraction, challenges remain in arid regions with complex surface features to develop extraction frameworks that balance efficiency and accuracy at a regional scale. This study focuses on the Inner Mongolia Yellow River Basin and develops a PV extraction framework on the Google Earth Engine platform by integrating spectral bands, spectral indices, and topographic features, systematically comparing the classification performance of support vector machine, classification and regression tree, and random forest (RF) classifiers. The results show that the RF classifier achieved a high Kappa coefficient (0.94) and F1 score (0.96 for PV areas) in PV extraction. Feature importance analysis revealed that the Normalized Difference Tillage Index, near-infrared band, and Land Surface Water Index made significant contributions to PV classification, accounting for 10.517%, 6.816%, and 6.625%, respectively. PV stations are mainly concentrated in the northern and southwestern parts of the study area, characterized by flat terrain and low vegetation cover, exhibiting a spatial pattern of "overall dispersion with local clustering". Landscape pattern indices further reveal significant differences in patch size, patch density, and aggregation level of PV stations across different regions. This study employs Sentinel-2 imagery for regional-scale PV station extraction, providing scientific support for energy planning, land use optimization, and ecological management in the study area, with potential for application in other global arid regions.