Dew is an important water source for vegetation growth in arid regions and plays a significant role in maintaining ecosystem balance. The characteristics of dew formation vary under different topographic conditions. In response to the challenges posed by climate change to the sustainability of water resources and ecosystems, this study explored the impact of topography on dew formation, and leaf wetness sensors (LWSs) were employed to conduct field observations from April 2023 to April 2025 in typical hilly and gully regions of China's Loess Plateau. We analyzed the characteristics, influencing factors, and ecological significance of near-surface water vapor condensation. The main conclusions are as follows: (1) During the observation period, dew primarily occurred between 19:00 and 07:00 the next day, peaking between 05:30 and 07:00 in the early morning. The monthly average dew amounts for the hilly region and gully region were 2.15 mm and 3.38 mm, respectively, and the monthly maximum dew amounts were 8.57 mm and 11.88 mm, respectively, both peaking in autumn, with the gully region exhibiting higher dew amounts. (2) Dew formation at a 0.2 m height was favored when relative humidity at 0.2 m exceeded 70%, the air temperature-dew point difference was less than 8 degrees C, the wind direction was between 150 and 210 degrees and 240 and 270 degrees for the hilly region and gully region, respectively, and the standardized wind speed at a 10 m height was less than 0.5 m/s and 1.5 m/s for the hilly region and gully region, respectively. (3) Moderate rainfall facilitates dew condensation. The monthly average dew-to-precipitation (dew and rain) ratio reached its maximum in November for both the Loess hilly region and gully region, at 12.88% and 18.91%, respectively. (4) The gully region experienced larger dew events more frequently than the hilly region, resulting in a higher overall dew amount in the gully region during the observation period. The dew formation characteristics observed in this study can provide a scientific basis for assessing the future supply potential of non-precipitation water sources in the Loess Plateau under climate change and their supporting role in the ecological environment.