China's North-South Transition Zone is a critical ecological transition region, marked by complex environments, climatic sensitivity, and transitional characteristics. To investigate the effects of individual rainfall events on runoff generation and sediment yield across different slopes and land uses within this zone, the study collected data from slope runoff plots (20 m in length and 5 m in width, measured as horizontal projection) at three monitoring stations (Luoshan, Lushan, Shanzhou) between 2014 and 2023. Rainfall events were classified via K-means clustering. Regression and correlation analyses were applied to reveal the effects of rainfall characteristics, slope gradient and land use type (grass land, dry land, forest land, bare land and natural vegetation) on runoff and sediment. The results indicate that: (1) The most frequent rainstorms were Type C (short, low-intensity, low-volume, low-erosivity events). (2) The runoff depth of bare land is 3.6, 2.3, and 2 times that of forest land, dry land, and natural vegetation, respectively. Similarly, its sediment concentration is 134, 13, and 16 times higher, respectively. Grassland, however, showed markedly lower levels of both runoff and sediment. (3) Rainfall intensity was significantly correlated with runoff and sediment across slopes. Runoff depth depended mainly on rainfall amount. While Type A (prolonged, high-intensity) caused peak runoff, Type D (moderate but intense and erosive) yielded the highest sediment. (4) Sediment reduction efficiency (sediment reduction compared to bare land under identical conditions) consistently surpassed runoff reduction across all land types, with grassland showing the highest efficiency for both. For soil and water conservation, grass-planting was the most effective measure on 10 degrees and 15 degrees slopes, whereas both afforestation and grass-planting were optimal on the 25 degrees slopes.