Karst regions are commonly characterized by highly interwoven bare rock-bare soil-vegetation mosaics, strong coupling between surface and subsurface processes, and pronounced geomorphic fragmentation. Conventional land cover classification systems, which are primarily organized around land use patterns or generic ecological types, are often unable to accurately represent these key surface components and their roles in ecological processes. From the perspective of reconstructing classification semantics, this study proposes a Natural-Attribute-Based Karst Land Cover Classification framework (NALCC). The framework takes bare rock, bare soil, vegetation, water bodies, and impervious surfaces as primary classes, and further develops a hierarchical system consisting of subclasses, attribute labels, hierarchical coding, multi-scale organization, and parameter mapping with ecosystem service models. Compared with conventional land cover classification systems, the innovation of this framework lies not in increasing the number of categories, but in reconstructing the semantic organization of classification units, so that land cover classification can move beyond surface-type description toward the expression of process-sensitive information. The classification objective of NALCC is not to develop a universal land cover classification system, but to establish a process-oriented classification framework for ecosystem service monitoring, rocky desertification diagnosis, and governance zoning in karst regions, which can directly represent key surface components and their ecological-process significance. However, its regional transferability and mapping performance still need to be further validated through case studies in representative areas.