Soil quality is a critical determinant of crop productivity. This study assessed the soil quality of 61 barley farmlands in central and northern Hubei Province based on ten soil chemical properties: pH, soil organic matter (SOM), ammonium nitrogen (NH4+-N), nitrate nitrogen (NO3--N), hydrolyzable nitrogen (HN), available phosphorus (AP), available potassium (AK), exchangeable calcium (Exc-Ca), exchangeable magnesium (Exc-Mg), and available sulfur (AS). A total of 68.85% of the farmlands were acidic (pH < 6.5). The average levels of SOM, NH4+-N, NO3--N, and HN were deficient, while AP was moderate, according to the Second State Soil Survey of China (SSSSC). AK, Exc-Ca, Exc-Mg, and AS were, on average, at moderate-to-abundant levels. Differences in preceding crops led to significant differences in pH and SOM between paddy and dryland fields. A minimum data set was established using six soil properties (HN, AS, AK, Exc-Ca, Exc-Mg, and NH4+-N) to calculate the soil quality index (SQI). SQI ranged from 0.27 to 0.69, with an average of 0.45, indicating overall low soil quality in the region. Both accuracy importance and R-2-weighted importance revealed that HN was the most influential factor driving SQI variation among the soil properties examined. This study elucidates the status of soil nutrients, offering a diagnostic basis for developing targeted fertilization strategies for barley in this region.