Geochemical evolution and elemental behaviour of playa sediments: impacts of natural weathering and agricultural practices

Playas are predominantly alkaline wetlands common in arid and semi-arid regions. These unique ecosystems are heavily influenced by climatic and hydrological processes, such as high evapotranspiration rates and negative water balance. Numerous studies have documented the ecological degradation of these saline ecosystems due to both anthropogenic and natural processes. The present research analyses the mineralogical and elemental changes in six representative playas at different degradation stages in the western External Betics. Chemical weathering and element fractionation were examined to identify the key geochemical factors involved in the degradation of these playa wetlands. A novel methodology for calculating the Fractionation Index (FI) has been developed and applied alongside established geochemical indices, such as the Chemical Index of Alteration (CIA), Chemical Index of Weathering (CIW), and Vogt's Residual Index (VRI), as well as analyses of elemental distribution. This approach allows for a comprehensive differentiation of the geochemical processes occurring in nonsaline-alkali, saline-alkali, and degraded playas. The study highlights the role of alkalinity in promoting clay mineral formation, with Na+ and Ca2+ dominating the cationic composition. These findings provide insights into the dynamics of playa ecosystems and inform conservation strategies for managing these vulnerable environments. Las lagunas tipo playa son humedales predominantemente alcalinos, comunes en regiones & aacute;ridas y semi & aacute;ridas. Estos ecosistemas & uacute;nicos est & aacute;n fuertemente condicionados por procesos clim & aacute;ticos e hidrol & oacute;gicos, como las altas tasas de evapotranspiraci & oacute;n y el balance h & iacute;drico negativo. Numerosos estudios han documentado la degradaci & oacute;n ecol & oacute;gica de estos ecosistemas salinos debido tanto a procesos antr & oacute;picos como naturales. La presente investigaci & oacute;n analiza los cambios mineral & oacute;gicos y elementales en seis lagunas tipo playa representativas, en diferentes etapas de degradaci & oacute;n, situadas en el sector occidental de las B & eacute;ticas Externas. Se examinaron la meteorizaci & oacute;n qu & iacute;mica y la fraccionaci & oacute;n elemental para identificar los principales factores geoqu & iacute;micos implicados en la degradaci & oacute;n de estos humedales. Se ha desarrollado y aplicado una metodolog & iacute;a novedosa para el c & aacute;lculo del & Iacute;ndice de Fraccionamiento (Fractionation Index, FI), junto con & iacute;ndices geoqu & iacute;micos ya establecidos, como el & Iacute;ndice Qu & iacute;mico de Alteraci & oacute;n (Chemical Index of Alteration, CIA), el & Iacute;ndice Qu & iacute;mico de Meteorizaci & oacute;n (Chemical Index of Weathering, CIW) y el & Iacute;ndice Residual de Vogt (Vogt's Residual Index, VRI), as & iacute; como an & aacute;lisis de la distribuci & oacute;n elemental. Este enfoque permite una diferenciaci & oacute;n integral de los procesos geoqu & iacute;micos que tienen lugar en playas no salinas-alcalinas, salinas-alcalinas y degradadas. El estudio destaca el papel de la alcalinidad en la promoci & oacute;n de la formaci & oacute;n de minerales de arcilla, con Na+ y Ca-2(+) como cationes dominantes en la composici & oacute;n. Estos resultados aportan informaci & oacute;n valiosa sobre la din & aacute;mica de los ecosistemas lagunares y contribuyen al dise & ntilde;o de estrategias de conservaci & oacute;n para la gesti & oacute;n de estos entornos vulnerables.